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Stresses in Glass Produced by Nonuniform Exchange of Monovalent Ions
Author(s) -
KISTLER S. S.
Publication year - 1962
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1962.tb11081.x
Subject(s) - ion , soda lime , alkali metal , materials science , leaching (pedology) , soda lime glass , diffusion , ultimate tensile strength , composite material , mineralogy , chemistry , inorganic chemistry , analytical chemistry (journal) , thermodynamics , chromatography , environmental science , physics , organic chemistry , soil science , soil water
A study was made of the rate of diffusion of alkali ions into a soda‐lime glass from nitrate melts, and the distortion of glass disks produced by the stresses thus developed was measured using an interference technique. A maximum of 124,000 psi was produced when Na + was replaced by K + . Tensile stresses accompanying the replacement of a large ion by a smaller one or by leaching ions out of the surface with water or dilute acid may be large and can destroy the glass.

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