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Characterization of Sinterable Oxide Powders: I, BeO
Author(s) -
QUIRK J. F.,
MOSLEY N. B.,
DUCKWORTH W. H.
Publication year - 1957
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1957.tb12565.x
Subject(s) - calcination , sintering , materials science , thermal decomposition , ceramic , oxide , chemical engineering , mineralogy , decomposition , impurity , metallurgy , composite material , chemistry , catalysis , biochemistry , organic chemistry , engineering
The discovery of readily sinterable BeO powder facilitated the production of dense, high‐strength BeO ceramics and created interest in the properties and preparation of sinterable BeO. BeO powders prepared by the thermal decomposition of Be(OH) 2 were studied in an effort to relate sinterability with other more basic characteristics of the oxide powder. Different BeO powders made from analyzed hydroxides showed a wide range of sinterability. The temperatures required for sintering the powder compacts to theoretical density ranged from 2300° to above 3200°F. Lattice parameters, thermal decomposition, surface areas, and refractive indices were determined on these powders after calcination in air at 750°, 1470°, 1830°, and 2190°F. Although unexpected variations in these properties were observed, no simple relation with sinterability was found. Occluded and surface impurities appeared to have a critical effect on sintering behavior.