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Observations and impacts of bleach washing on indoor chlorine chemistry
Author(s) -
Wong J. P. S.,
Carslaw N.,
Zhao R.,
Zhou S.,
Abbatt J. P. D.
Publication year - 2017
Publication title -
indoor air
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.387
H-Index - 99
eISSN - 1600-0668
pISSN - 0905-6947
DOI - 10.1111/ina.12402
Subject(s) - hypochlorous acid , chlorine , bleach , chemistry , chloramine , environmental chemistry , aerosol , chloride , ozone , bromine , inorganic chemistry , organic chemistry
Ambient levels of chlorinated gases and aerosol components were measured by online chemical ionization and aerosol mass spectrometers after an indoor floor were repeatedly washed with a commercial bleach solution. Gaseous chlorine (Cl 2 , 10's of ppbv) and hypochlorous acid ( HOC l, 100's of ppbv) arise after floor washing, along with nitryl chloride (Cl NO 2 ), dichlorine monoxide (Cl 2 O), and chloramines ( NHC l 2 , NC l 3 ). Much higher mixing ratios would prevail in a room with lower and more commonly encountered air exchange rates than that observed in the study (12.7 h −1 ). Coincident with the formation of gas‐phase species, particulate chlorine levels also rise. Cl 2 , Cl NO 2 , NHC l 2 , and NC l 3 exist in the headspace of the bleach solution, whereas HOC l was only observed after floor washing. HOC l decays away 1.4 times faster than the air exchange rate, indicative of uptake onto room surfaces, and consistent with the well‐known chlorinating ability of HOC l. Photochemical box modeling captures the temporal profiles of Cl 2 and HOC l very well and indicates that the OH , Cl, and ClO gas‐phase radical concentrations in the indoor environment could be greatly enhanced (>10 6 and 10 5 cm −3 for OH and Cl, respectively) in such washing conditions, dependent on the amount of indoor illumination.