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Anticorrosion assessment of Al 2 O 3 ‐TiO 2 composite thin films derived from sol‐gel dipping technique
Author(s) -
Oliaee Seyyed Alireza,
Naghibi Sanaz
Publication year - 2017
Publication title -
international journal of applied ceramic technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.4
H-Index - 57
eISSN - 1744-7402
pISSN - 1546-542X
DOI - 10.1111/ijac.12849
Subject(s) - materials science , calcination , coating , corrosion , tafel equation , indentation hardness , amorphous solid , surface roughness , composite number , ceramic , composite material , rutile , metallurgy , chemical engineering , microstructure , electrochemistry , organic chemistry , electrode , engineering , catalysis , biochemistry , chemistry
Metal surface protection by means of nanostructured ceramic coatings is considered an issue, which is variously scrutinized, and more efforts are made to improve steel performance in accordance with this method. In this respect, this study sought to examine the protective effects of a nanostructured coating containing TiO 2 and Al 2 O 3 . The optimization approach for obtaining a coating without any cracks with the highest efficiency of corrosion resistance is reported. The variables under assessment were as follows: weight ratio of the oxides, calcination temperature, and preparation parameters. The synthesized samples were analyzed utilizing XRD , FESEM , AFM , Tafel test, EIS , and microhardness measurement. The results revealed that the optimized conditions were as follows: (i) Ti:Al precursor mixture with a weight ratio of 75:25, (ii) heat treatment at 1000°C. This process yielded a uniform composite coating without any cracks with 5.1 nm roughness, containing crystalline rutile phase and amorphous alumina. Not only the intended coating improves the corrosion resistance of steel up to 97%, but it also increases its surface hardness up to 10 units.