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Assessment of repeatability of composition of perfumed waters by high‐performance liquid chromatography combined with numerical data analysis based on cluster analysis ( HPLC UV / VIS – CA )
Author(s) -
Ruzik L.,
Obarski N.,
Papierz A.,
Mojski M.
Publication year - 2015
Publication title -
international journal of cosmetic science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 62
eISSN - 1468-2494
pISSN - 0142-5463
DOI - 10.1111/ics.12195
Subject(s) - repeatability , high performance liquid chromatography , chromatography , composition (language) , chemistry , cluster (spacecraft) , analytical chemistry (journal) , computer science , philosophy , linguistics , programming language
Synopsis High‐performance liquid chromatography ( HPLC ) with UV / VIS spectrophotometric detection combined with the chemometric method of cluster analysis ( CA ) was used for the assessment of repeatability of composition of nine types of perfumed waters. In addition, the chromatographic method of separating components of the perfume waters under analysis was subjected to an optimization procedure. The chromatograms thus obtained were used as sources of data for the chemometric method of cluster analysis ( CA ). The result was a classification of a set comprising 39 perfumed water samples with a similar composition at a specified level of probability (level of agglomeration). A comparison of the classification with the manufacturer's declarations reveals a good degree of consistency and demonstrates similarity between samples in different classes. A combination of the chromatographic method with cluster analysis ( HPLC UV / VIS – CA ) makes it possible to quickly assess the repeatability of composition of perfumed waters at selected levels of probability.