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Arsenic Remediation Field Study Using a Sulfate Reduction and Zero‐Valent Iron PRB
Author(s) -
Beaulieu Brett,
Ramirez Rachel Elena
Publication year - 2013
Publication title -
groundwater monitoring and remediation
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.677
H-Index - 47
eISSN - 1745-6592
pISSN - 1069-3629
DOI - 10.1111/gwmr.12007
Subject(s) - arsenic , sulfate , zerovalent iron , environmental remediation , environmental chemistry , chemistry , sulfide , ferric , pyrite , arsenate , environmental engineering , environmental science , contamination , adsorption , inorganic chemistry , mineralogy , ecology , organic chemistry , biology
Toxic and carcinogenic effects of arsenic in drinking water continue to impact people throughout the world and arsenic remains common in groundwater at cleanup sites and in areas with natural sources. Advances in groundwater remediation are needed to attain the low concentrations that are protective of human health and the environment. In this article, we present the successful use of a permeable reactive barrier ( PRB ) utilizing sulfate reduction coupled with zero‐valent iron ( ZVI ) to remediate the leading edge of a dissolved arsenic plume in a wetland area near Tacoma, Washington. A commercially available product ( EHC ‐M®, Adventus Americas Inc., Freeport, Illinois) that contains ZVI , organic carbon substrate, and sulfate was injected into a reducing, low‐seepage‐velocity aquifer elevated in dissolved arsenic and iron from a nearby, slag‐containing landfill. Removal effectiveness was strongly correlated with sulfate concentration, and was coincident with temporary redox potential (Eh) reductions, consistent with arsenic removal by iron sulfide precipitation. The PRB demonstrates that induced sulfate reduction and ZVI are capable of attaining a regulatory limit of 5 µg/L total arsenic, capturing of 97% of the arsenic entering the PRB , and sustaining decreased arsenic concentrations for approximately 2 years, suggesting that the technology is appropriate for consideration at other sites with similar hydrogeochemical conditions. The results indicate the importance of delivery and longevity of minimum sulfate concentrations and of maintaining sufficient dissolved organic carbon and/or microscale ZVI to precipitate FeS , a precursor phase to arsenic‐bearing pyrite that may provide a stable, long‐term sink for arsenic.