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Chemical and Mineralogical Mapping of Platinum‐Group Element Ore Samples Using Laser‐Induced Breakdown Spectroscopy and Micro‐X‐Ray Fluorescence
Author(s) -
Mohamed Nessrine,
Rifai Kheireddine,
Selmani Samira,
Constantin Marc,
Doucet François R.,
Özcan Lütfü Ç.,
Sabsabi Mohamad,
Vidal François
Publication year - 2021
Publication title -
geostandards and geoanalytical research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.037
H-Index - 73
eISSN - 1751-908X
pISSN - 1639-4488
DOI - 10.1111/ggr.12385
Subject(s) - laser induced breakdown spectroscopy , platinum group , chalcopyrite , pentlandite , mineralogy , sulfide , mineral , pyrite , pyrrhotite , silicate minerals , analytical chemistry (journal) , sulfide minerals , geology , mineral redox buffer , silicate , chemistry , spectroscopy , materials science , geochemistry , metallurgy , platinum , environmental chemistry , copper , biochemistry , quantum mechanics , mantle (geology) , catalysis , physics , organic chemistry
Standard techniques for geochemical and mineralogical characterisation are time‐consuming, they can involve significant sample preparation and they are prone to error. The aim of this work is to show how the emerging fast laser‐induced breakdown spectroscopy (LIBS) technique can be valuable for mineral exploration. For this purpose, the well‐established micro‐X‐ray fluorescence (µ‐XRF) technique was used to validate the LIBS data. Two ore samples from the platinum‐group elements (PGE) Lac des Îles mine (Ontario, Canada) were analysed both by LIBS and µ‐XRF. The fast mineralogical and elemental mapping provided by LIBS allowed the identification of four major silicate phases (chlorite, bytownite, actinolite, hornblende) and four minor sulfide phases (Pd‐bearing pentlandite, chalcopyrite, pyrrhotite, pyrite). Multi‐element chemical mapping and mineral characterisation using µ‐XRF corroborated the LIBS analyses for the composition, distribution and abundance of minerals in PGE ore samples. These findings demonstrate the ability of the LIBS technique to perform direct fast high‐resolution mapping of the chemical and mineralogical composition of PGE ore samples. This work highlights the advantages of LIBS for this application of being much faster and more sensitive to trace elements (e.g., Pd), as well as to low atomic number elements.