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Unexpected spatial stability of water chemistry in headwater stream networks
Author(s) -
Abbott Benjamin W.,
Gruau Gérard,
Zarnetske Jay P.,
Moatar Florentina,
Barbe Lou,
Thomas Zahra,
Fovet Ophélie,
Kolbe Tamara,
Gu Sen,
PiersonWickmann AnneCatherine,
Davy Philippe,
Pinay Gilles
Publication year - 2018
Publication title -
ecology letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.852
H-Index - 265
eISSN - 1461-0248
pISSN - 1461-023X
DOI - 10.1111/ele.12897
Subject(s) - environmental science , hydrology (agriculture) , streams , aquatic ecosystem , spatial variability , ecosystem , ecology , nutrient , anthropocene , drainage basin , disturbance (geology) , temporal scales , water chemistry , dissolved organic carbon , geology , geography , biology , computer network , paleontology , statistics , geotechnical engineering , mathematics , cartography , environmental engineering , computer science
Understanding how water and solutes enter and propagate through freshwater landscapes in the Anthropocene is critical to protecting and restoring aquatic ecosystems and ensuring human water security. However, high hydrochemical variability in headwater streams, where most carbon and nutrients enter river networks, has hindered effective modelling and management. We developed an analytical framework informed by landscape ecology and catchment hydrology to quantify spatiotemporal variability across scales, which we tested in 56 headwater catchments, sampled periodically over 12 years in western France. Unexpectedly, temporal variability in dissolved carbon, nutrients and major ions was preserved moving downstream and spatial patterns of water chemistry were stable on annual to decadal timescales, partly because of synchronous variation in solute concentrations. These findings suggest that while concentration and flux cannot be extrapolated among subcatchments, periodic sampling of headwaters provides valuable information about solute sources and subcatchment resilience to disturbance.

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