Premium
A fourfold interpenetrating three‐dimensional cadmium(II) coordination polymer: synthesis, crystal structure and physical properties
Author(s) -
Wu Ji-Pei,
Cheng Yi-Chuan,
Lu Lei,
Wang Jun,
Qiao Shan-Bao
Publication year - 2021
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229621004642
Subject(s) - thermogravimetric analysis , cadmium , naphthalene , coordination polymer , methylene , ether , crystal structure , crystallography , chemistry , single crystal , fluorescence , materials science , nuclear chemistry , medicinal chemistry , organic chemistry , physics , quantum mechanics
A novel three‐dimensional Cd II coordination framework, namely, poly[{μ‐bis[4‐(2‐methylimidazol‐1‐yl)phenyl] ether‐κ 2 N 3 : N 3′ }(μ‐naphthalene‐1,4‐dicarboxylato‐κ 3 O 1 : O 4 , O 4′ )cadmium(II)], [Cd(C 12 H 6 O 4 )(C 20 H 18 N 4 O)] n or [Cd(1,4‐NDC)(BMIOPE)] n , where 1,4‐H 2 NDC is naphthalene‐1,4‐dicarboxylic acid and BMIOPE is bis[4‐(2‐methylimidazol‐1‐yl)phenyl] ether, has been prepared and characterized by single‐crystal X‐ray diffraction, elemental analysis, IR spectroscopy and thermogravimetric analysis. The compound displays a novel fourfold interpenetrating diamond‐like network. In addition, it not only shows a strong fluorescence emission in the solid state, but also exhibits excellent photocatalytic activity for the degradation of methylene blue (MB) at room temperature.