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A fourfold interpenetrating diamond‐like three‐dimensional zinc(II) coordination polymer: synthesis, crystal structure and physical properties
Author(s) -
Chen Hui-Ru
Publication year - 2019
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229619004303
Subject(s) - zinc , coordination polymer , crystallography , crystal structure , fluorescence , hydrate , polymer , diamond , infrared spectroscopy , metal , single crystal , elemental analysis , chemistry , materials science , inorganic chemistry , organic chemistry , physics , quantum mechanics
Excellent fluorescence properties are exhibited by d 10 metal compounds. The novel three‐dimensional Zn II coordination framework, poly[[{μ 2 ‐bis[4‐(2‐methyl‐1 H ‐imidazol‐1‐yl)phenyl] ether‐κ 2 N 3 : N 3′ }(μ 2 ‐furan‐2,5‐dicarboxylato‐κ 2 O 2 : O 5 )zinc(II)] 1.76‐hydrate], {[Zn(C 6 H 2 O 5 )(C 20 H 18 N 4 O)]·1.76H 2 O} n , has been prepared and characterized using IR spectroscopy, elemental analysis and single‐crystal X‐ray diffraction. The crystal structure analysis revealed that the compound exhibits a novel fourfold interpenetrating diamond‐like network. This polymer also displays a strong fluorescence emission in the solid state at room temperature.