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A novel three‐dimensional Sr II coordination polymer based on benzene‐1,2,4,5‐tetracarboxylate: hydrothermal synthesis, crystal structure and spectroscopic and thermal studies
Author(s) -
Trifa Chahrazed,
Mokhtari Samia,
Bouacida Sofiane,
Boudaren Chaouki,
Boudraa Mhamed,
Merazig Hocine
Publication year - 2017
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229617003850
Subject(s) - square antiprism , crystallography , strontium , coordination polymer , thermal decomposition , crystal structure , hydrothermal synthesis , chemistry , infrared spectroscopy , binodal , benzene , polymer , dodecahedron , hydrothermal circulation , materials science , ion , lanthanide , phase (matter) , organic chemistry , seismology , phase diagram , geology
Coordination of the anions of benzenecarboxylic acids with metal cations leads to coordination polymers with various structural features. Very few examples of strontium‐based structures have been reported. A new three‐dimensional coordination polymer, namely poly[aqua(μ 12 ‐benzene‐1,2,4,5‐tetracarboxylato)distrontium(II)], [Sr 2 (C 10 H 2 O 8 )(H 2 O)] n , has been synthesized under hydrothermal conditions and characterized by thermal analysis, vibrational spectroscopy (Raman and IR), single‐crystal X‐ray diffraction and powder X‐ray diffraction. The coordination geometries around the two independent Sr II ions can be described as a distorted dodecahedron and a distorted monocapped square antiprism. The compound features a three‐dimensional structure containing inorganic motifs, with two‐dimensional layers connected through organic linkers, and possesses a topologic structure of a binodal (6,12) connected alb net with the Schläfli symbol {4 15 } 2 {4 48 .6 18 }. The final product of thermal decomposition is strontium oxide (SrO).