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A helical zinc(II) coordination polymer assembled from 1,3‐bis[(pyridin‐3‐yl)methoxy]benzene and benzene‐1,4‐dicarboxylic acid
Author(s) -
Yu CaiXia,
Ma FengJi,
Liu LeiLei,
Liu Cong
Publication year - 2014
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229614025546
Subject(s) - benzene , dicarboxylic acid , zinc , coordination polymer , chemistry , polymer , polymer chemistry , medicinal chemistry , organic chemistry
In catena ‐poly[[aqua[1,3‐bis(pyridine‐3‐ylmethoxy)benzene‐κ N ]zinc(II)]‐μ 2 ‐benzene‐1,4‐dicarboxylato‐κ 2 O 1 : O 4 ], [Zn(C 8 H 4 O 4 )(C 18 H 16 N 2 O 2 )(H 2 O)] n , each Zn II centre is tetrahedrally coordinated by two O atoms of bridging carboxylate groups from two benzene‐1,4‐dicarboxylate anions (denoted L 2− ), one O atom from a water molecule and one N atom from a 1,3‐bis[(pyridin‐3‐yl)methoxy]benzene ligand (denoted bpmb). (Aqua)O—H...N hydrogen‐bonding interactions induce the formation of one‐dimensional helical [Zn( L )(bpmb)(H 2 O)] n chains which are interlinked through (aqua)O—H...O hydrogen‐bonding interactions, producing two‐dimensional corrugated sheets.