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A three‐dimensional cadmium(II) coordination polymer: poly[[[μ‐4,4′‐(propane‐1,3‐diyl)dipyridine‐κ 2 N : N ](μ‐3,3′‐thiodipropionato‐κ 3 O , O ′: O )cadmium(II)] monohydrate]
Author(s) -
Hao XiaoMin,
Chen Gang,
Gu ChangSheng,
Liu JiWei
Publication year - 2014
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229614013011
Subject(s) - propane , carboxylate , octahedron , crystallography , atom (system on chip) , chemistry , coordination polymer , stereochemistry , crystal structure , organic chemistry , computer science , embedded system
In the title coordination polymer, {[Cd(C 6 H 8 O 4 S)(C 13 H 14 N 2 )]·H 2 O} n , the Cd II atom displays a distorted octahedral coordination, formed by three carboxylate O atoms and one S atom from three different 3,3′‐thiodipropionate ligands, and two N atoms from two different 4,4′‐(propane‐1,3‐diyl)dipyridine ligands. The Cd II centres are bridged through carboxylate O atoms of 3,3′‐thiodipropionate ligands and through N atoms of 4,4′‐(propane‐1,3‐diyl)dipyridine ligands to form two different one‐dimensional chains, which intersect to form a two‐dimensional layer. These two‐dimensional layers are linked by S atoms of 3,3′‐thiodipropionate ligands from adjacent layers to form a three‐dimensional network.