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The inorganic–organic hybrid zinc phosphite poly[(μ 3 ‐hydrogen phosphito‐κ 3 O : O ′: O ′′)(piperidin‐1‐ium‐4‐carboxylate‐κ O )zinc(II)]
Author(s) -
Wang GuoMing,
Zhao XiaoMeng,
Zhang Xiao,
Bao ZhenZhen
Publication year - 2014
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229614003118
Subject(s) - carboxylate , zinc , protonation , chemistry , hydrolysis , crystal structure , piperidine , crystallography , stereochemistry , chirality (physics) , inorganic chemistry , organic chemistry , chiral symmetry , nambu–jona lasinio model , physics , quantum mechanics , quark , ion
A new inorganic–organic hybrid zinc phosphite, [Zn(HPO 3 )(C 6 H 11 NO 2 )] n , has been synthesized hydrothermally. Protonated piperidin‐1‐ium‐4‐carboxylate (PDCA) was generated in situ by hydrolysis of the piperidine‐4‐carboxamide precursor. The P atom possesses a typical PO 3 H pseudo‐pyramidal geometry. The crystal structure features an unusual (3,4)‐connected two‐dimensional inorganic zinc–phosphite layer, with organic PDCA ligands appended to the sheets and protruding into the interlayer region. Helical chains of opposite chirality are involved in the construction of a puckered sheet structure.