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The coordination polymer poly[[aqua(μ‐oxalato)[1 H ‐1,2,4‐triazole‐5(4 H )‐thione]cadmium(II)] monohydrate]
Author(s) -
Liang Qian,
Wang YuLin,
Zhao Yan,
Cao GaoJuan
Publication year - 2014
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229614000102
Subject(s) - oxalate , chemistry , hydrogen bond , ligand (biochemistry) , 1,2,4 triazole , molecule , cadmium , triazole , carboxylate , metal , stereochemistry , crystallography , medicinal chemistry , inorganic chemistry , organic chemistry , receptor , biochemistry
The title complex, {[Cd(C 2 O 4 )(C 2 H 3 N 3 S)(H 2 O)]·H 2 O} n , has a two‐dimensional metal–organic framework, with the Cd II cation coordinated by three oxalate ligands, a 1 H ‐1,2,4‐triazole‐5(4 H )‐thione (H 2 trzS) ligand and a water molecule. The CdO 6 S and oxalate units form an extended two‐dimensional layered structure, with the terminal H 2 trzS ligands bonded to the Cd II sites through the thione S atoms. Hydrogen‐bond interactions exist between adjacent layers.