Premium
Nanodomains and local structure in ternary alkaline‐earth hexaborides
Author(s) -
Koch Robert,
Metz Peter C.,
Jaime Oscar,
Vargas-Consuelos C. Ingram,
Borja-Urby Raúl,
Ko J. Y. Peter,
Cahill James T.,
Edwards Doreen,
Vasquez Victor R.,
Graeve Olivia A.,
Misture Scott T.
Publication year - 2018
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s1600576718012657
Subject(s) - raman spectroscopy , ternary operation , pair distribution function , materials science , reverse monte carlo , spectroscopy , monte carlo method , transmission electron microscopy , raman scattering , analytical chemistry (journal) , boron , lattice (music) , crystallography , chemistry , crystal structure , nanotechnology , optics , physics , neutron diffraction , statistics , mathematics , organic chemistry , chromatography , quantum mechanics , computer science , acoustics , programming language
The local structures of ternary alkaline‐earth hexaborides ( M B 6 , M = Ca 0.5 Sr 0.5 , Ca 0.5 Ba 0.5 and Sr 0.5 Ba 0.5 ) have been analysed using X‐ray pair distribution function (PDF) analysis, Raman spectroscopy and transmission electron microscopy (TEM). The results show significant local deviations from the average cubic structure within the boron sub‐lattice and support the conclusion that rapid synthesis processes lead to the formation of coherent nanodomains over length scales of about 10 nm. Reverse Monte Carlo fitting of the PDFs allows for quantification of the displacement disorder within the boron sub‐lattice as a function of sample composition. Detailed Raman spectroscopy studies and high‐resolution TEM support the models derived from X‐ray scattering. The average magnitude of the static displacement disorder varies by sample composition and positively correlates with the cation radius ratios across the three compositions. The new models form a foundation for future computational and experimental studies aimed at understanding and predicting properties of hexaborides.