Open Access(μ‐Diazenediyldiphenyl‐κ 2 C 2 , N 2 :κ 2 C 2′ , N 1 )bis[(3,5‐dimethylphenyl)tellurium(II)]
Author(s) -
Mallikaratchy Prabodhika,
Norman Richard E.,
Fronczek Frank R.,
Junk Thomas
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536805018659
Subject(s) - tellurium , chemistry , crystallography , physics , inorganic chemistry
The title compound, C 28 H 26 N 2 Te 2 , prepared by reduction of (3,5‐dimethylphenyl)(2‐nitrophenyl)tellurium(II), is the first structurally characterized example of an azo group bridging two Te II centers. The compound is centrosymmetric and the Te—N distance [2.6916 (19) Å] is longer than in non‐bridging azo compounds.
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