Temperature dependence of photoelectron angular distribution from thin films of chloroaluminum phthalocyanine on MoS 2 | Zendy

Azuma Yasushi | Zendy; Tsutsui Masahiko | Zendy; Kera Satoshi | Zendy; Aoki Masaru | Zendy; Miyamae Takayuki | Zendy; Okudaira Koji K. | Zendy; Harada Yoshiya | Zendy; Ueno Nobuo | Zendy

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Temperature dependence of photoelectron angular distribution from thin films of chloroaluminum phthalocyanine on MoS 2

Author(s) -

Azuma Yasushi,

Tsutsui Masahiko,

Kera Satoshi,

Aoki Masaru,

Miyamae Takayuki,

Okudaira Koji K.,

Harada Yoshiya,

Ueno Nobuo

Publication year - 1998

Publication title -

journal of synchrotron radiation

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.172

H-Index - 99

ISSN - 1600-5775

DOI - 10.1107/s0909049597016889

Subject(s) - phthalocyanine , thin film , materials science , x ray photoelectron spectroscopy , analytical chemistry (journal) , chemistry , physics , nanotechnology , organic chemistry , nuclear magnetic resonance

Angle‐resolved UV photoelectron spectra were measured for thin films of chloroaluminum phthalocyanine deposited on cleaved MoS 2 surfaces. The take‐off angle (θ) dependence of the photoelectron intensity of the highest π band showed a remarkable sharpening upon cooling the film, indicating that thermal excitation of molecular vibrations gives a considerable broadening of the photoelectron angular distribution. The θ dependence observed at ∼120 K agrees well with that calculated.

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