Open AccessLi K ‐edge spectra of lithium halides
Author(s) -
Tsuji J.,
Kojima K.,
Ikeda S.,
Nakamatsu H.,
Mukoyama T.,
Taniguchi K.
Publication year - 2001
Publication title -
journal of synchrotron radiation
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.172
H-Index - 99
ISSN - 1600-5775
DOI - 10.1107/s090904950001791x
Subject(s) - halide , spectral line , synchrotron radiation , lithium (medication) , k edge , atomic orbital , valence (chemistry) , chemistry , absorption edge , atomic physics , absorption spectroscopy , lithium atom , molecular orbital , valence electron , electron , materials science , physics , molecule , ion , optics , inorganic chemistry , band gap , ionization , medicine , optoelectronics , organic chemistry , quantum mechanics , astronomy , endocrinology
We measured the Li K‐edge spectra of lithium halides by means of total electron yield method (TEY), using the soft x‐ray Beam Line 2 (BL2) of the compact synchrotron radiation facility at Ritsmeikan University in Japan. In lithium halides, the spectra have a sharp peak at about 60eV and a broad peak at the higher energy side. Various peak structures that appear in the absorption spectra are assigned to the corresponding Li‐1s to valence band free orbitals transitions, which have been calculated by the Discrete Variational (DV)‐Xα molecular orbital calculation method.