Open AccessPolarization dependence of resonant X‐ray emission spectra in early transition metal compounds
Author(s) -
Matsubara Masahiko,
Uozumi Takayuki,
Kotani Akio
Publication year - 2001
Publication title -
journal of synchrotron radiation
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.172
H-Index - 99
ISSN - 1600-5775
DOI - 10.1107/s0909049500016538
Subject(s) - spectral line , polarization (electrochemistry) , emission spectrum , electron , transition metal , atomic physics , x ray , metal , chemistry , physics , materials science , optics , quantum mechanics , astronomy , catalysis , biochemistry , organic chemistry
We calculate the polarization dependent spectra of resonant X‐ray emission in TiF 3 , VF 3 and Cr 2 O 3 , which have one, two and three 3 d electron(s) in the ground state, respectively. We study the detailed mechanism of the spectral structures, comparing with a previous result of TiO 2 . Then we discuss systematically the difference of spectra with the change of the 3 d electron number from group theoretical consideration.