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A reaction cell for in situ studies of hydrothermal titration
Author(s) -
Norby P.,
Cahill C.,
Koleda C.,
Parise J. B.
Publication year - 1998
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s002188989701337x
Subject(s) - reagent , titration , in situ , hydrothermal circulation , hydrothermal reaction , yield (engineering) , precipitation , diffraction , chemistry , ion exchange , ion , materials science , analytical chemistry (journal) , crystallography , inorganic chemistry , chemical engineering , chromatography , optics , organic chemistry , metallurgy , physics , meteorology , engineering
A reaction cell for in situ studies of both ion‐exchange and hydrothermal titration reactions has been designed and built. This cell allows the injection of reagents into a reaction mixture over time during X‐ray data collection. A demonstration experiment followed the injection of Na 2 SO 4 (aq) into BaCl 2 (aq) to yield a time‐resolved X‐ray powder diffraction pattern of the precipitation of BaSO 4 (s).