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Parameterizations of scattering intensities and values of the angularities and of the interphase surfaces for three‐component amorphous samples
Author(s) -
Ciccariello S.,
Benedetti A.
Publication year - 1985
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s0021889885010184
Subject(s) - interphase , scattering , amorphous solid , intensity (physics) , component (thermodynamics) , radiation , volume fraction , materials science , function (biology) , simple (philosophy) , computational physics , fraction (chemistry) , correlation function (quantum field theory) , chemistry , physics , statistical physics , mathematics , optics , thermodynamics , crystallography , statistics , chromatography , philosophy , genetics , epistemology , evolutionary biology , biology , spectral density
Different functional parameterizations of the radiation intensity scattered by an N ‐component amorphous sample are considered. Each parameterization is such that (i) it depends only on the areas and on the angularities of the samples' interphase surfaces, (ii) it fulfils all the known physical constraints and (iii) it yields a rather simple algebraic expression both for the correlation function and for the scattered intensity. The parameterizations have been used for analysing the scattering data relevant to some three‐component catalysts. Provided the volume fraction of the metal is not very small, the best fit yields satisfactory results only for some of the considered parameterizations. In this way, the determination of both the areas and the angularities of catalysts appears possible.