Crystal data for 7HgI 2 Fe(C 5 H 5 ) 2 | Zendy

Votinský J. | Zendy; Beneš L. | Zendy; Klikorka J. | Zendy; Kalousová J. | Zendy; Horák J. | Zendy; Loš P. | Zendy

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Crystal data for 7HgI 2 Fe(C 5 H 5 ) 2

Author(s) -

Votinský J.,

Beneš L.,

Klikorka J.,

Kalousová J.,

Horák J.,

Loš P.

Publication year - 1984

Publication title -

journal of applied crystallography

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.429

H-Index - 162

ISSN - 1600-5767

DOI - 10.1107/s0021889884011699

Subject(s) - tetragonal crystal system , vapours , powder diffraction , diffraction , crystallography , materials science , iodide , x ray crystallography , orthorhombic crystal system , crystal structure , space group , analytical chemistry (journal) , chemistry , inorganic chemistry , physics , optics , chromatography , neuroscience , biology

The new compound 7HgI 2 .Fe(C 5 H 5 ) 2 was prepared by the reaction of solid tetragonal mercuric iodide with ferrocene vapours at 423 K. The product is a dark green powder, stable in air, and decomposes at 463 K. The cubic unit‐cell parameters (298 K) are: a = 20.12(2) Å, V = 8157.3 Å 3 , Z = 8, M r = 3366.8, D x = 5.49 Mg m −3 ; extinctions indicate a face‐centered space group. X‐ray (Cu Kα radiation) powder diffraction data (50 lines) are reported. The compound has interesting electrical properties. The JCPDS Diffraction File No. for 7HgI 2 .Fe(C 5 H 5 ) 2 is 35‐2000.

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