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A new optical method and apparatus `HAUP' for measuring simultaneously optical activity and birefringence of crystals. II. Application to triglycine–sulphuric acid (NH 2 CH 2 CO 2 H) 3 .H 2 SO 4
Author(s) -
Kobayashi J.,
Uesu Y.,
Takehara H.
Publication year - 1983
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s0021889883010274
Subject(s) - birefringence , ferroelectricity , gyration , dielectric , triglycine sulfate , polarization (electrochemistry) , electric field , optical rotation , chemistry , hysteresis , condensed matter physics , optics , materials science , analytical chemistry (journal) , nuclear magnetic resonance , physics , optoelectronics , organic chemistry , mathematics , quantum mechanics , geometry
As the test for the utility of HAUP, simultaneous determinations of birefringence, optical activity, and rotation of the indicatrix, and electrooptic, and electrogyration coefficients were made for both paraelectric and ferroelectric states of triglycine‐sulfuric acid, 3C 2 H 5 NO 2 .H 2 SO 4 . In the ferroelectric state, the hysteresis loop of the gyration tensor g 22 was clearly observed. Electrooptic and electrogyration coefficients referred to polarization are found to be nearly independent of temperature over the paraelectric and ferroelectric states. It is important to note that gyration is more largely induced than birefringence under lower electric fields. This fact, contrary to the previous belief, indicates that simultaneous determinations of gyration and birefringence are indispensable for the correct evaluations of the optical properties of crystals.