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Crystal data for antimony molybdenum oxide Sb 2 MoO 6
Author(s) -
Laarif A.,
Hewat A.,
Theobald F.,
Vivier H.
Publication year - 1983
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s0021889883010122
Subject(s) - triclinic crystal system , monoclinic crystal system , antimony , fluorite , crystallography , molybdenum , crystal structure , octahedron , materials science , chemistry , metallurgy
The powder data for antimony molybdenum oxide Sb 2 MoO 6 are reported. This compound is triclinic, P , with a = 7.481(4), b = 7.504(3), c = 10.120(1) Å, α = 70.43(3), β = 70.91(4), γ = 83.34(7)°; U = 505.9(5) Å 3 ; Z = 4; D x = 5.74 Mg m −3 . The structure is of the fluorite type but it is distorted. Pseudo‐monoclinic cells as reported by Parmentier, Courtois & Gleitzer [ Bull. Soc. Chim. Ft. (1974), 1–2 , 75–77] or that obtained with program TRACER [Lawton & Jacobson (1965). Mobil Oil Corporation Research Department; Lawton (1967). Mobil Oil Corporation Research Department] are also considered and discussed. Neutron diffraction gives further evidence of the triclinic lattice. The JCPDS Diffraction File No. for Sb 2 MoO 6 is 33–1491.