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Crystal data for the oxidation product of bis(2,2'‐bipyridyl)copper(I) perchlorate in nitroalkanes
Author(s) -
Garland M. T.,
Spodine E.,
Zamudio W.
Publication year - 1981
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s0021889881009862
Subject(s) - perchlorate , copper , chemistry , crystal (programming language) , crystal structure , crystallography , single crystal , inorganic chemistry , ion , organic chemistry , computer science , programming language
Single crystals of [Cu(bpy) 2 NO 2 ]ClO 4 , [Cu(C 10 H 8 N 2 ) 2 NO 2 ]ClO 4 , C 20 H 16 CuN 5 O 2 .ClO 4 , with space group P 2 1 / c , were grown from the reacting mixture of bis(2,2′‐bipyridyl)copper(I) perchlorate with molecular oxygen in nitroalkanes. The unit‐cell parameters are a = 10.83 (2), b = 12.51 (1), c = 17.04 (1) Å, β = 112.0 (2)°, Z = 4, D m = 1.62 (1) Mg m −3 .