Premium
Coordination d'anions organophosphorés. IV. Préparation et identification cristallographique de différentes phases de nitratocomplexes du cobalt(II), du nickel(II) et du zinc(II)
Author(s) -
Youinou M.T.,
Guerchais J.E.
Publication year - 1976
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s0021889876011151
Subject(s) - monoclinic crystal system , chemistry , zinc , nickel , cobalt , crystallography , crystal structure , metal , stereochemistry , inorganic chemistry , organic chemistry
Chemical preparations and crystal data are described for the new nitratocomplexes {M(NO3)L} where M 2+ is a metallic ion Co 2+ , Ni 2+ , Zn 2+ and L − the anion {(C 2 H 5 O) 2 P(O)CHCOCH 2 R} − with R an amino group. The isolation of one or many crystalline forms depends on the nature of the radical R. These different species have been characterized by their space groups and the powder patterns of the monoclinic forms have been indexed from the single‐crystal dimensions.