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Crystal data for the complexes of triphenylphosphine oxide (TPPO) and benzyldiphenylphosphine oxide (BDPPO) with cobalt (II) thiocyanate
Author(s) -
Leite C. R.,
Barelli N.,
Massabni A. C.
Publication year - 1976
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s0021889876010492
Subject(s) - triphenylphosphine oxide , thiocyanate , cobalt , chemistry , crystallography , crystal (programming language) , oxide , triphenylphosphine , crystal structure , inorganic chemistry , organic chemistry , computer science , programming language , catalysis
Crystal data for TPPO and BDPPO complexes with cobalt (II) thiocyanate, space group R 32 ( a = 17.50±0.06 Å, b = 30.99±0.08 Å) and Pbcn ( a = 10.10±0.01 Å; b = 20.22±0.03 Å; c = 18.94±0.01 Å), respectively, suggest C 2 as the only compatible symmetry for both complexes. Optical, morphological and X‐ray powder data are given.