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X‐ray scattering effects of ionic size in solid solutions KCl–KBr
Author(s) -
Luova P.,
Tuominen P.,
VanhaKämppä P.
Publication year - 1970
Publication title -
journal of applied crystallography
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.429
H-Index - 162
ISSN - 1600-5767
DOI - 10.1107/s0021889870006465
Subject(s) - ionic radius , ionic bonding , solid solution , ion , scattering , chemistry , x ray , distortion (music) , analytical chemistry (journal) , chloride , ionic crystal , materials science , optics , physics , chromatography , amplifier , optoelectronics , organic chemistry , cmos
The diffuse X‐ray scattering from single crystals of 36:64 and 50:50 KCl–KBr solid solutions has been studied. The analysis of the results, which follows the method described by Borie, is based on the approximation of a solid solution Cl − –Br − . The observed values of the distortion constant for the chloride ion are 2–3 times greater than those calculated on the basis of the conventional values of ionic radii.