X‐ray scattering effects of ionic size in solid solutions KCl–KBr | Zendy

Luova P. | Zendy; Tuominen P. | Zendy; VanhaKämppä P. | Zendy

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X‐ray scattering effects of ionic size in solid solutions KCl–KBr

Author(s) -

Luova P.,

Tuominen P.,

VanhaKämppä P.

Publication year - 1970

Publication title -

journal of applied crystallography

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.429

H-Index - 162

ISSN - 1600-5767

DOI - 10.1107/s0021889870006465

Subject(s) - ionic radius , ionic bonding , solid solution , ion , scattering , chemistry , x ray , distortion (music) , analytical chemistry (journal) , chloride , ionic crystal , materials science , optics , physics , chromatography , amplifier , optoelectronics , organic chemistry , cmos

The diffuse X‐ray scattering from single crystals of 36:64 and 50:50 KCl–KBr solid solutions has been studied. The analysis of the results, which follows the method described by Borie, is based on the approximation of a solid solution Cl − –Br − . The observed values of the distortion constant for the chloride ion are 2–3 times greater than those calculated on the basis of the conventional values of ionic radii.

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