Different crystal chemistries of the117 C d → 117
Author(s) -
Y. Ohkubo,
Yukihiro Murakami,
Tadashi Saito,
Akihiko Yokoyama,
S. Uehara,
Seiichi Shibata,
Yōichi Kawase
Publication year - 1999
Publication title -
physical review. b, condensed matter
Language(s) - English
Resource type - Journals
eISSN - 1095-3795
pISSN - 0163-1829
DOI - 10.1103/physrevb.60.11963
Subject(s) - differential (mechanical device) , crystal (programming language) , materials science , molecular physics , atomic physics , physics , thermodynamics , computer science , programming language
The temperature dependences of the nuclear-electric-quadrupole frequency vQ of 117In doped in LiTaO3(TC5938 K) and Li12xInx/3TaO3 with x50.2 (TC5818 K) show that the order-disorder of the Li ions is notthe driving mechanism for the ferroelectric instability in LiNbO3 and LiTaO3 systems, and imply that theoxygen order-disorder is the driving mechanism. The significantly different temperature dependences of vQ of111Cd in these materials compared, to those of 117In, demonstrate that this order-disorder is of dynamiccharacter
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