f-fandf-dtransition interference inSm2+:SrFCl | Zendy

Raivo Jaaniso | Zendy; H. Bill | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

f-fandf-dtransition interference inSm2+:SrFCl

Author(s) -

Raivo Jaaniso,

H. Bill

Publication year - 1991

Publication title -

physical review. b, condensed matter

Language(s) - English

Resource type - Journals

eISSN - 1095-3795

pISSN - 0163-1829

DOI - 10.1103/physrevb.44.2389

Subject(s) - physics , excited state , order (exchange) , coupling (piping) , crystallography , state (computer science) , combinatorics , atomic physics , condensed matter physics , materials science , algorithm , chemistry , mathematics , finance , economics , metallurgy

The 5D3(4f6)-7F0(4f6) transition of Sm2+ in SrFCl is found to be anomalously strong and it exhibits an asymmetric line shape, which is interpreted in terms of resonant interaction between the 5D3 excited state and the vibronic levels of a low-lying 4f55d electronic state. The electronic coupling strength is estimated to be of the order of 100 cm-1. The symmetry species of interacting levels are identified, and the possibility of an E×(b1+b2) type of Jahn-Teller effect in the 4f55d state is discussed

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research