Phase diagram of a lattice model for ternary mixtures of water, oil, and surfactants
Author(s) -
Mohamed Laradji,
Hong Guo,
Martin Grant,
Martin J. Zuckermann
Publication year - 1991
Publication title -
physical review a
Language(s) - English
Resource type - Journals
eISSN - 1094-1622
pISSN - 1050-2947
DOI - 10.1103/physreva.44.8184
Subject(s) - phase diagram , physics , microemulsion , monte carlo method , lattice (music) , thermodynamics , pulmonary surfactant , component (thermodynamics) , ternary operation , phase (matter) , statistical physics , condensed matter physics , quantum mechanics , statistics , mathematics , computer science , acoustics , programming language
We study a lattice model for a three-component system of water, oil, and surfactants in two dimensions. Large-scale Monte Carlo simulations were performed to obtain the phase equilibria for a wide range of temperatures and surfactant concentrations. We show that this model has a rich phase behavior, and both microemulsion and liquid crystalline phases were found. The phase behavior is consisent with that of a real system, and is in qualitative agreement with the model of Gompper and Schick [Phys. Rev. Lett. 62, 1647 (1989)], which is based on three-body interactions
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