Open AccessBulk superconductivity in Pb-substituted BiS$_{\bf 2}$-based compounds studied by hard-x-ray spectroscopyOpen Access
Author(s)
A. Yamasaki,
T. Oguni,
T. Hayashida,
K. Miyazaki,
N. Tanaka,
K. Nakagawa,
K. Tamura,
K. Mimura,
N. Kawamura,
H. Fujiwara,
G. Nozue,
A. Ose,
Y. Kanai-Nakata,
A. Higashiya,
S. Hamamoto,
K. Tamasaku,
M. Yabashi,
T. Ishikawa,
S. Imada,
A. Sekiyama,
H. Sakata,
S. Demura
Publication year2024
In this study, we investigate the bulk electronic structure of Pb-substitutedLaO$_{0.5}$F$_{0.5}$BiS$_2$ single crystals, using two types of hard-x-rayspectroscopy. High-energy-resolution fluorescence-detected x-ray absorptionspectroscopy revealed a spectral change at low temperatures. Using densityfunctional theory (DFT) simulations, we find that the temperature-inducedchange originates from a structural phase transition, similar to thepressure-induced transition in LaO$_{0.5}$F$_{0.5}$BiS$_2$. This findingsuggests that the mechanism of bulk superconductivity induced by Pbsubstitution is the same as that under high pressure. Furthermore, a novellow-valence state with a mixture of divalent and trivalent Bi ions isdiscovered using hard x-ray photoemission spectroscopy with the aid of DFTcalculations.
Language(s)English
DOI10.1103/physrevb.109.045131
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