Open AccessHydrogen production by the photoreforming of methanol and the photocatalytic water–gas shift reaction
Author(s) -
Julia Kennedy,
James Hayward,
Philip R. Davies,
Michael Bowker
Publication year - 2021
Publication title -
jphys energy
Language(s) - English
Resource type - Journals
ISSN - 2515-7655
DOI - 10.1088/2515-7655/abdd82
Subject(s) - water gas shift reaction , methanation , catalysis , methanol , chemistry , hydrogen , hydrogen production , dissolution , carbon monoxide , photocatalysis , inorganic chemistry , stoichiometry , water gas , syngas , organic chemistry
We have examined the reforming of methanol and CO on Pd/P25 TiO 2 catalysts for hydrogen production, and compared it with rates for similarly supported Au and Cu catalysts. Both reactions proceed, but the photocatalytic water–gas shift (WGS) reaction is much slower than for methanol reforming. CO 2 is evolved as expected, but the yields can be much lower than for the expected stoichiometry (CH 3 OH + H 2 O → CO 2 + 3H 2 ). We show that this is due to dissolution of the carbon dioxide into the aqueous phase. We have also carried out both reactions in the gas phase. Both proceed at a higher rate in the gas phase, and for methanol reforming, there is some CO evolution. In H 2 + CO 2 reactions, there is little sign of the reverse WGS reaction, but some photo-methanation does occur. Of the three catalysts Pd is the best for the methanol reforming reaction, while Au is best for the water–gas shift. Nonetheless, Cu works reasonably well for methanol reforming and makes a much cheaper, earth-abundant catalyst.