Open AccessGreen synthesis of cobalt oxide nanoparticles and the effect of annealing temperature on their physiochemical and biological properties
Author(s) -
Sirajul Haq,
Farwah Abbasi,
Manel Ben Ali,
Amor Hedfi,
Amine Mezni,
Wajid Rehman,
Muhammad Waseem,
Abdul Rehman Khan,
Hamayun Shaheen
Publication year - 2021
Publication title -
materials research express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.383
H-Index - 35
ISSN - 2053-1591
DOI - 10.1088/2053-1591/ac1187
Subject(s) - calcination , fourier transform infrared spectroscopy , diffractometer , nuclear chemistry , materials science , absorbance , scanning electron microscope , cobalt , cobalt oxide , amorphous solid , nanoparticle , analytical chemistry (journal) , chemistry , chemical engineering , nanotechnology , organic chemistry , chromatography , catalysis , engineering , metallurgy , composite material
The cobalt oxide nanoparticles (Co 3 O 4 NPs) were synthesized via the green method using Piper nigrum ( P. nigrum ) leaves extract and were calcined at different temperatures. The crystalline nature was studied through x-ray diffractometer (XRD). With increasing calcination, the amorphous phase transitioned to the crystalline phase. Diffuse reflectance spectroscopy (DRS) was used to observe UV-Visible light absorbance phenomenon, and Tauc’s plot was used to calculate the band gap energy, which was found to decrease with calcination. Scanning electron microscopy (SEM) was used to analyze the surface morphology, and Fourier transform infrared (FTIR) spectroscopy was used to classify the surface functional groups. The antibacterial efficacy of the Co 3 O 4 NPs was examined against Gram-positive bacteria (GPB) and Gram-negative bacteria (GNB), whereas its antioxidant potential was explored against ABTS free radicals. Antibacterial and antioxidant potentials of Co 3 O 4 NPs were found to decrease with increasing calcination.