Open AccessEffect of Cu2+ ions on structural, morphological, optical and magnetic behaviors of ZnAl2O4 spinel
Author(s) -
T. Sofia Nirmala,
N. Iyandurai,
S. Yuvaraj,
M. Sundararajan
Publication year - 2020
Publication title -
materials research express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.383
H-Index - 35
ISSN - 2053-1591
DOI - 10.1088/2053-1591/ab7a7a
Subject(s) - spinel , materials science , copper , zinc , analytical chemistry (journal) , paramagnetism , nanoparticle , doping , chemistry , nanotechnology , metallurgy , optoelectronics , physics , chromatography , quantum mechanics
Zn 1−x Cu x Al 2 O 4 nanoparticles were prepared by microwave combustion technique with metal nitrates as precursor materials. Powder x-ray diffraction studies confirm the formation of single phase of spinel pure and copper doped zinc aluminates. HR-SEM images reveal the agglomerated coalescence morphology with pores. Elemental analysis (EDX) confirm the presence of Zn, Cu, Fe and O. UV-Visible Diffuse reflectance spectroscopy is used to find the optical bandgap and it is found to decreases from 5.45 eV to 3.57 eV. IR spectra show three major peaks which confirm the phase formation of Zn 1−x Cu x Al 2 O 4 nano aluminates with spinel structure. Vibrating sample magnetometer (VSM) measurements reveal the super paramagnetic nature of pure and copper doped zinc alumintes. The obtain results are confirmed that present pure and copper doped ZnAl 2 O 4 particles at nanoscale are to be potential candidate for catalytic, sensor and optoelectronic device applications.