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Effect of pH on visible-light-driven photocatalytic degradation of facile synthesized bismuth vanadate nanoparticles
Author(s) -
A. Juliat Josephine,
C. Ravi Dhas,
R. Venkatesh,
D. Arivukarasan,
Ashton Christy,
S. Esther Santhoshi Monica,
S. Keerthana
Publication year - 2020
Publication title -
materials research express
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.383
H-Index - 35
ISSN - 2053-1591
DOI - 10.1088/2053-1591/ab653f
Subject(s) - bismuth vanadate , photocatalysis , vanadate , x ray photoelectron spectroscopy , materials science , raman spectroscopy , nanoparticle , rhodamine b , monoclinic crystal system , visible spectrum , precipitation , absorption (acoustics) , rhodamine 6g , fourier transform infrared spectroscopy , chemical engineering , nuclear chemistry , nanotechnology , chemistry , crystal structure , catalysis , crystallography , optics , metallurgy , molecule , organic chemistry , physics , optoelectronics , meteorology , engineering , composite material
Bismuth vanadate (BiVO 4 ) nanoparticles were synthesized by a simple co-precipitation method for different pH conditions (9, 10 and 11). The XRD patterns revealed that the synthesized nanoparticles belong to monoclinic single-phase BiVO 4 which was again confirmed from Raman studies. The chemical state of the elements in BiVO 4 and surface morphology were investigated using XPS and SEM analysis respectively. The optical absorption and PL studies revealed wide absorption in the visible region with strong emission at 520 nm. The efficiency of the samples was examined from the photocatalytic degradation of Rhodamine B dye.