Open AccessSimulation of the Sb2Se3 solar cell with a hole transport layer
Author(s) -
Zhenqi Li,
Ming Ni,
Xiaodong Feng
Publication year - 2020
Publication title -
materials research express
Language(s) - English
Resource type - Journals
ISSN - 2053-1591
DOI - 10.1088/2053-1591/ab5fa7
Subject(s) - materials science , solar cell , work function , electrode , doping , schottky barrier , optoelectronics , metal , layer (electronics) , capacitance , analytical chemistry (journal) , antimony , schottky diode , nanotechnology , chemistry , metallurgy , diode , chromatography
A model of the Sb 2 Se 3 solar cell with a hole transport layer (HTL) has been investigated by solar cell capacitance simulator (SCAPS). The influence of different HTLs on device performance has been firstly analyzed, and CuO has been found to be the best HTL. Then, Sb 2 Se 3 thickness, CuO thickness, the doping concentration of CuO, the hole mobility of CuO, the defect density of Sb 2 Se 3 layer, the defect density at the CdS/Sb 2 Se 3 interface, and the work function of metal electrode on device performance have been systematically studied. The optimum thicknesses of Sb 2 Se 3 and CuO are 300 nm and 20 nm, respectively. To achieve ideal performance, the doping concentration of CuO should be more than 10 19 cm −3 , and its hole mobility should be over 1 cm 2 V −1 s −1 . The defect densities in the Sb 2 Se 3 layer and at the CdS/ Sb 2 Se 3 interface play a critical role on device performance, both of which should be as low as 10 13 cm −3 and 10 14 cm −2 , respectively. In addition, the work function of the metal electrode should be more than 4.8 eV to avoid formation of Schottky junction at the metal electrode interface. After optimization, a best efficiency of 23.18% can be achieved. Our simulation results provide valuable information to further improve the efficiency of Sb 2 Se 3 solar cells in practice.