Open AccessOptimisation and characterisation studies of biodiesel production from black soldier fly larvae fed by soya residue
Author(s) -
Azlan Kamari,
S Ishak,
M I A M Hussin,
Syie Luing Wong,
J Jumadi,
N M Yahaya
Publication year - 2020
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/980/1/012057
Subject(s) - biodiesel , methanol , central composite design , biodiesel production , response surface methodology , gas chromatography , transesterification , fourier transform infrared spectroscopy , pulp and paper industry , chemistry , vegetable oil , yield (engineering) , residue (chemistry) , materials science , chromatography , waste management , catalysis , chemical engineering , organic chemistry , composite material , engineering
In this study, a two-step transesterification process was applied to convert crude BSF larval oil into biodiesel. The effects of methanol:oil (molar ratio), catalyst amount (weight %), reaction time (minutes) and temperature (°C) on biodiesel production were investigated. Central Composite Design (CCD) of Response Surface Methodology (RSM) was used to optimise experimental data obtained from these four variables. The prediction of biodiesel yield was made by employing a quadratic model, whereby the R 2 values were greater than 0.99. Based on optimisation studies, a combination of an application of petroleum ether and reaction time of 6 hours was the best to extract crude larval oil with 47% of lipid yield. Meanwhile, methanol:oil molar ratio of 12:1, catalyst (NaOH) concentration of 1.0 weight %, a reaction time of 32 minutes and temperature of 60°C were required to obtain biodiesel with 96% of production yield from BSF crude larval oil. Both BSF crude larval oil and biodiesel were characterised using several analytical instruments such as Fourier Transform Infrared (FTIR) spectrometer and Gas Chromatography – Flame Ionisation Detector (GC-FID). Overall, findings from this study highlight the potential to produce eco-friendly biodiesel from BSF larvae reared on soya residue.