Open AccessKinetic study for the co-pyrolysis of water hyacinth biomass with waste polystyrene
Author(s) -
C. Phiwchaaum,
Bussarin Ksapabutr,
Nattawut Chaiyut,
Manop Panapoy
Publication year - 2020
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/965/1/012029
Subject(s) - pyrolysis , activation energy , thermogravimetric analysis , chemistry , chemical engineering , biomass (ecology) , diffusion , polystyrene , decomposition , kinetic energy , waste management , materials science , organic chemistry , polymer , thermodynamics , oceanography , physics , engineering , geology , quantum mechanics
Co-pyrolysis behavior of water hyacinth (WHC) and waste PS using thermogravimetric analysis to determine kinetic parameters was investigated. TG and DTG results indicated that the pyrolysis of WHC and mixture of WHC and waste PS could be divided into three stages. It was found that co-pyrolysis of WHC and waste PS delayed the pyrolysis process with a wider decomposition temperature range, when compared with the pyrolysis of PS. The results compared with the pyrolysis of individual components revealed a positive synergistic interaction between WHC and waste PS according to the difference in weight loss. Coats-Redfern method was applied in the second stage to evaluate the activation energy (Ea) and pre-exponential factor (A) from the data of weight loss using three major reaction mechanisms. Two conversion temperature zones, zone I of 240-400 °C and zone II of 400-530 °C, were identified and a best-fit model describing the co-pyrolysis behavior of mixture was achieved. The addition of waste PS to WHC led to a slight decrease in the activation energy in the first zone and then the activation energy significantly reduced in the second zone. Chemical reaction and diffusion-controlled reaction mechanisms could be kinetically examined and enabled good explanation of the co-pyrolysis behavior of the mixture of WHC and waste PS as well as individual pyrolysis.