TiO2/Co3O4 nanocomposite: Synthesis via Catharanthus roseus (L.) G. Don leaf extract, characterization and its photocatalytic activity for malachite green degradation
Author(s) -
Tri Wahyuni Widiyas Syahfitri,
Yoki Yulizar,
Jarnuzi Gunlazuardi,
Dewangga Oky Bagus Apriandanu
Publication year - 2020
Publication title -
iop conference series materials science and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.179
H-Index - 26
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/902/1/012003
Subject(s) - malachite green , nanocomposite , nuclear chemistry , photocatalysis , materials science , catharanthus roseus , degradation (telecommunications) , nanoparticle , visible spectrum , chemistry , nanotechnology , catalysis , organic chemistry , adsorption , telecommunications , biochemistry , computer science , optoelectronics
TiO 2 /Co 3 O 4 nanocomposite was successfully synthesized using leaf extract of Catharanthus roseus (L.) G. Don. (CRE), precursors of TTIP and Co(NO 3 ) 2 . FT-IR characterization shows that TiO 2 /Co 3 O 4 has been formed due to the presence of secondary metabolites in CRE which have a major role as a weak base source for nanocomposite synthesis. Particle size analysis was employed by PSA and TEM, which were found to be 38.04 nm and 90.80 nm, respectively. Besides, the UV-Vis DRS result shows that TiO 2 /Co 3 O 4 has bandgap energy at 2.8 eV. According to the morphological analysis, TiO 2 /Co 3 O 4 nanocomposite has a spherical shape confirmed by SEM. The structural analysis was confirmed by XRD that TiO 2 /Co 3 O 4 nanocompositehas a diffraction pattern combination of TiO 2 and Co 3 O 4 nanoparticle. The photocatalytic activity of TiO 2 /Co 3 O 4 nanocomposite was examined for malachite green degradation. The result shows that the degradation percentage was 82.61 % under visible light illumination for 120 min.
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