Open AccessThermal transformations in polymineral technogenic cement raw
Author(s) -
Olga Miryuk
Publication year - 2020
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/889/1/012025
Subject(s) - belite , andradite , alite , skarn , periclase , mineralogy , cement , magnetite , metallurgy , raw material , geology , grossular , clinker (cement) , mineral , materials science , chemical composition , portland cement , chemistry , magnesium , quartz , fluid inclusions , organic chemistry
The results of physicochemical studies of composition and thermal transformations of large-tonnage wastes of skarn-magnetite ore dressing in Kazakhstan are presented. To determine materials’ composition of the following methods were used: X-ray, differential and thermal, Mössbauer and infrared spectroscopy. The stepwise nature of transformation of anthropogenic material during firing, due to polymineral composition of ore dressing wastes is revealed. Provides information on the chemical and mineral composition, thermal transformations of ore dressing wastes. It has been established that the chemical-mineral characteristics of natural silicates determine formation processes and properties of clinker phases. The features of the formation of clinker phases with the participation of the technogenic component of the raw mix, which consist in the activity of low-temperature interactions, the variety of intermediate phases are revealed. It has been established that the staging of belite formation with the participation of actinolite, albite, andradite, grossular, diopside, chlorite, epidote is due to gradual transformations of minerals into intermediate phases C 2 AS, C 3 MS 2 , of which C 2 S is formed at temperatures of 1000-1300oC. Alite formation is intensified due to high-temperature belite formation and doping impurities. Skarn-magnetite ores wastes are an effective cement raw material, providing high-quality portland cement clinker using low-energy and resource-saving technology.