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Synthesis and Characterization of Cationic Waterborne Epoxy Acrylic Resin
Author(s) -
Hongbo Liu,
Xiaowu Xue,
Wuying Zhang,
Feng Lin
Publication year - 2020
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/774/1/012048
Subject(s) - epoxy , acrylic acid , bisphenol a , cationic polymerization , fourier transform infrared spectroscopy , synthetic resin , acrylic resin , isocyanate , titration , polymer chemistry , nuclear chemistry , chemistry , materials science , organic chemistry , chemical engineering , polyurethane , polymer , copolymer , coating , engineering
In this work, a cationic waterborne epoxy acrylic resin (WCEA) was synthesized from bisphenol an epoxy resin, acrylic acid, acrylic acid, hydroquinone as an inhibitor, and N, N-dimethylbenzylamine (DMBA) as a catalyst. The changes of NCO groups and acid value during the synthesis process were measured by chemical titration method, and its Fourier Transform Infrared (FTIR) spectra were investigated. The results indicate that the acidified waterborne resin has great water solubility and storage stability after grafting the half-blocked isocyanate.

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