Open AccessPolystyrene-supported nickel complex catalysed deprotection of allylic tertiary amine with sodium borohydride
Author(s) -
Lingxiang Bao,
Honggang Liang,
Haonan Zhang,
Zhibin Yan,
ChiaChung Sun,
Siping Pang
Publication year - 2020
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/772/1/012101
Subject(s) - sodium borohydride , allylic rearrangement , polystyrene , catalysis , nickel , amine gas treating , reusability , environmentally friendly , chemistry , x ray photoelectron spectroscopy , metal , organic chemistry , polymer chemistry , materials science , chemical engineering , polymer , ecology , software , computer science , engineering , biology , programming language
This work represents a green and facile approach for the polystyrene supported nickel catalysed deprotection of allylic tertiary amine. The careful instrumental investigations with XPS, TEM, TGA, XRD and ICP-AES precisely characterized the developed heterogeneous catalyst. Cheap metal, mild reaction conditions, good yields as well as the reusability of the catalyst made this method more environmentally friendly.