
Investigation of sorption characteristics of modified klinoptilolites by the method of infra-red energy and differential X-ray spectroscopy
Author(s) -
М В Обуздина,
E.A. Rush
Publication year - 2020
Publication title -
iop conference series materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/760/1/012046
Subject(s) - sorption , sorbent , adsorption , epichlorohydrin , sulfur , infrared spectroscopy , desorption , spectroscopy , x ray , chemistry , metal , analytical chemistry (journal) , materials science , inorganic chemistry , polymer chemistry , environmental chemistry , organic chemistry , physics , optics , quantum mechanics
The article presents investigations of adsorption of heavy metal ions Ni 2+ , Zn 2+ , Cu 2+ by modified zeolites. As a modifier of zeolites of the Holinsky deposit, a sulfur polymer is proposed that is obtained from waste during the production of epichlorohydrin, the main components of which is 1,2,3 - trichloropropane. The mechanisms of adsorption and the results of investigations by the methods of infra-red pectroscopy and energy differential X-ray spectroscopy of the initial samples of materials are described in detail. On the IR- spectres new absorption bands are considered. These bands reflect the nature of fixation of modifier on the surface of sorbent.
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