Open AccessPreparation of Polyvinyl Alcohol/Cellulose Nano fiber Nanocomposite Isolated from Empty Oil Palm Fruit Bunches
Author(s) -
Saharman Gea,
. Indra,
Yugia Muis,
Nami Panindia,
Yasir Arafat Hutapea
Publication year - 2019
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/553/1/012041
Subject(s) - polyvinyl alcohol , cellulose , nanofiber , materials science , hydrolysis , nanocomposite , ultimate tensile strength , acid hydrolysis , fiber , composite material , nuclear chemistry , chemical engineering , polymer chemistry , chemistry , organic chemistry , engineering
This research was aimed to manufacture polyvinyl alcohol (PVA)/cellulose nanofiber (CNF) nanocomposite which was isolated from oil palm empty fruit bunches (OPEFB) through steam explosion method combined with a hydrolysis process involving HCl 10%. The isolation process was performed in 2 steps; α-cellulose isolation from empty fruit bunches fibers and then cellulose nanofiber isolation from α-cellulose which was hydrolyzed with acid using ultrasonicator and homogenized in rotational speed of 8000 rpm. The functional group and morphology of nanofibres cellulose were characterized. FT-IR spectrum resulted an absorptions for C-O-C group at wavelength of 1059.99 cm-1 which indicated a glycoside bond. Then, C-H group at 2900.94 cm-1 and O-H group at 3348.62 cm-1 were revealed to indicate the cellulose nanofiber. Moreover, TEM was used for morphological analysis and showing a decrease in fibres diameters after experiencing a chemical-mechanical treatment which lead to nanofibres with final diameter size of 20-30 nm. PVA/CNF nanocomposite with the percentage ratio of 80:20 gave a tensile strength of 17.41 Mpa and Modulus Young of 0.9 Gpa. Finally, the product was also morphologically analyzed with SEM and indicating an even distribution on the PVA surface.