Open AccessEffects of interphase boundary anisotropy on the three-phase growth dynamics in the β(In) – In2Bi – γ(Sn) ternary-eutectic system
Author(s) -
Samira Mohagheghi,
U. Hecht,
Sabine Bottin-Rousseau,
Silvère Akamatsu,
G Faivre,
Melis Şerefoğlu
Publication year - 2019
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/529/1/012010
Subject(s) - eutectic system , materials science , interphase , anisotropy , nucleation , microstructure , directional solidification , isotropy , phase (matter) , crystal (programming language) , crystallography , ternary operation , condensed matter physics , thermodynamics , metallurgy , optics , chemistry , physics , genetics , organic chemistry , computer science , biology , programming language
We present an experimental investigation on the effects of the interphase energy anisotropy on the formation of three-phase growth microstructures during directional solidification (DS) of the β(In)–In 2 Bi–γ(Sn) ternary-eutectic system. Standard DS and rotating directional solidification (RDS) experiments were performed using thin alloy samples with real-time observation. We identified two main types of eutectic grains (EGs): (i) quasi-isotropic EGs within which the solidification dynamics do not exhibit any substantial anisotropy effect, and (ii) anisotropic EGs, within which RDS microstructures exhibit an alternation of locked and unlocked microstructures. EBSD analyses revealed (i) a strong tendency to an alignment of the In 2 Bi and γ(Sn) crystals (both hexagonal) with respect to the thin-sample walls, and (ii) the existence of special crystal orientation relationships (ORs) between the three solid phases in both quasi-isotropic and anisotropic EGs. We initiate a discussion on the dominating locking effect of the In 2 Bi–β(In) interphase boundary during quasi steady-state solidification, and the existence of strong crystal selection mechanisms during early nucleation and growth stages.