Open AccessA study on magnetic and spin polarized electric transport properties of cation doped LaCaMnO3perovskite ceramic system
Author(s) -
Sam Rajan,
Jayakumari Isac
Publication year - 2021
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/1166/1/012005
Subject(s) - polaron , condensed matter physics , magnetization , materials science , orthorhombic crystal system , electrical resistivity and conductivity , paramagnetism , perovskite (structure) , ferromagnetism , doping , variable range hopping , crystal structure , crystallography , chemistry , magnetic field , thermal conduction , physics , electron , quantum mechanics , composite material
Thepoly-crystallineLa 0.5 Nd 0.15 Ca 0.35 MnO 3 has been synthesized by a conventional solid reaction method through the cation doping in LaCaMnO 3 . The analysis of the powder XRD of the composites revealed the formation of an orthorhombic structure in Pbnm space group. The cell parameters of the formed system has obtained and confirmed through Reitveld analysis and it is found to be a=5.4505,b=5.4457,c=7.6876.The lattice parameters and the spin ordering temperature T C of this system are decreasing due to Nd substitution. The ac and dc magnetization studies and resistivity measurements in ZFC and FC mode gives good understanding to the magnetic and electric transport properties of the doped system. The magnetization studies show a paramagnetic to ferromagnetic transition at a temperature below the critical temperature T C .The resistivity measurements reveals semiconducting to metallic transition below the temperature T MS . The temperature dependent transport nature shown in this system is one type of the correlated polaron hopping mechanism and it can be modeled by an adiabatic small polaron hopping(SPH) mechanism.