Open AccessEnhancement of photo luminescent and magnetic properties of surface modified zinc sulphide nanoparticles by manganese doping
Author(s) -
I.A. Shaikh,
Adhish V. Raval,
Dimple Shah
Publication year - 2021
Publication title -
iop conference series. materials science and engineering
Language(s) - English
Resource type - Journals
eISSN - 1757-899X
pISSN - 1757-8981
DOI - 10.1088/1757-899x/1126/1/012039
Subject(s) - crystallite , materials science , analytical chemistry (journal) , manganese , doping , nanoparticle , photoluminescence , zinc , absorption edge , band gap , absorption spectroscopy , absorption (acoustics) , particle size , ferromagnetism , nanotechnology , chemistry , optics , condensed matter physics , optoelectronics , metallurgy , physics , chromatography , composite material
In the current paper we have reported the structural, optical and magnetic properties of manganese doped (1% to 10%) zinc sulphide nanoparticles synthesised by simple chemical co-precipitation method at room temperature. The crystal structure of the synthesised nanoparticles has been confirmed by X-ray diffraction and the average crystallite size calculated by Scherrer formula was about 3.0 nm. A slight quenching in the crystallite size with the doping was also observed. The FESEM images showed spherical shape particles with uniform size distribution. The elemental composition of pure and manganese doped zinc sulphide was confirmed by EDAX attached to FESEM. The UV-Vis spectra has an absorption edge at 321 nm with sharp fall in the absorption confirming the particles of uniform size distribution with no shift in the absorption edge with the doping. The band gap widening was observed (4.4 eV) and the particle size (3.4 nm) calculated was by effective mass approximation. The photoluminescence spectra has wide emission spectra with the peaks at 397 nm, 414 nm and 487 nm with increase in the intensity with the doping concentration giving a peak at 1% of doping and decrease in emission intensity after that. The hysteresis curve shows the ferromagnetism and the saturation magnetisation increases with the doping concentration.