
Preparation and properties of polystyrene composites modified by macromolecule flame retardant DOPO-HQ
Author(s) -
Qi Chen,
Wei Xu,
Yingqiang Zhang
Publication year - 2021
Publication title -
iop conference series. earth and environmental science
Language(s) - English
Resource type - Journals
eISSN - 1755-1307
pISSN - 1755-1315
DOI - 10.1088/1755-1315/784/1/012019
Subject(s) - fire retardant , polystyrene , materials science , combustion , copolymer , fourier transform infrared spectroscopy , macromolecule , composite number , composite material , polymer chemistry , styrene , calorimetry , chemical engineering , chemistry , polymer , organic chemistry , biochemistry , physics , engineering , thermodynamics
A macromolecular flame retardant was firstly the group reaction of DOPO-HQ. The modified polystyrene ADOPO-HQ-co-PS was prepared by copolymerization of macromolecular flame retardant and styrene. Its chemical structure was analyzed by Fourier transform infrared (FT-IR). PS composite was prepared by adding it to the experimental formula, and the cone-shaped calorimetry experiment was carried out on the material. The results show that it has a better flame retardant performance than DOPO-HQ. The smoke generation rate is very small, the highest is 0.2m 2 /s, the CO production is very small, the highest is 0.007g/s, and the mass loss is the highest is 0.14g/s, which shows that the material is more environmentally friendly and stable during combustion.